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Beilstein J. Org. Chem. 2018, 14, 1413–1420, doi:10.3762/bjoc.14.118
Graphical Abstract
Scheme 1: Nucleophilic and π-electrophilic characters of organometallics depending on the central metals.
Scheme 2: Ni/Cr or Co/Cr-catalyzed NHK reaction.
Scheme 3: Functionalization of alkynes via carbocobaltation.
Scheme 4: Cyclization/borylation of alkynyl iodoarenes using the Co/Cr catalyst.
Scheme 5: Three-component coupling of aryl iodides, arenes, and aldehydes using Co/Cr catalyst (this work).
Scheme 6: Screening of aldehydes in the Co/Cr-catalyzed three-component coupling reaction. All yields are det...
Scheme 7: Screening of aryl iodides in the Co/Cr-catalyzed three-component coupling reaction. All yields are ...
Scheme 8: Screening of allenes in the Co/Cr-catalyzed three-component coupling reaction. All yields are deter...
Scheme 9: Reversed diastereoselectivity using allenyl ethers 5 and 6. a4-chlorobenzaldehyde was used instead ...
Scheme 10: Stoichiometric reaction of phenylchromium(II or III) reagents (reaction 1) and the three-component ...
Scheme 11: The origin of the diastereoselectivity in the present three-component coupling.
Scheme 12: Plausible reaction mechanism of the three-component coupling.
Beilstein J. Org. Chem. 2017, 13, 1816–1822, doi:10.3762/bjoc.13.176
Scheme 1: Reaction process.
Figure 1: ORTEP drawing of Z-4ai.
Scheme 2: Reaction mechanism.
Scheme 3: Isomerization of the stereochemistry of 4ai.
Scheme 4: Reaction of cycloalkane-1,2-diones with phenyl vinyl ketone (6a).
Scheme 5: Preparation and reactivity of the bisacylated Breslow intermediate 10.
Figure 2: ORTEP drawing of 10.
Scheme 6: Preparation of the iminium salt 12 and its reactivity.
Scheme 7: Resting state of the monoacylated Breslow intermediate C.